Meaning
Quantitative measurement of the extent to which a carbonaceous material has been transformed into a perfectly crystalline hexagonal graphite lattice. The degree of graphitization is typically derived from X-ray diffraction data, specifically the spacing between the 002 lattice planes. It represents the proximity of the material structure to the theoretical d-spacing of 3.354 angstroms.
Values are expressed as a percentage or a decimal fraction where zero indicates completely disordered carbon.
Material Performance
Structural order dictates the capacity and voltage profile of an anode. Higher values for the degree of graphitization generally correlate with improved lithium-ion intercalation capacity.
Analytical Method
Calculations utilize the Maire and Mering equation to convert d-spacing into a structural index. Sample preparation involves grinding the material to a fine powder to ensure uniform diffraction peaks. Instrumental broadening must be accounted for during the measurement of the peak width at half maximum.
Accuracy depends on the resolution of the detector and the stability of the X-ray source.
Sourcing Requirement
Procurement specifications often define a minimum threshold for this metric to ensure battery cycle life. Suppliers adjust the heat treatment temperature and duration to hit a specific degree of graphitization. Costs increase as the target moves closer to one hundred percent due to the higher energy demand.
A trade-off exists between the cost of extreme heat treatment and the resulting gain in energy density.