Meaning
Maximum allowable rate of water vapour transmission into a sealed battery enclosure. Engineers define the moisture ingress threshold to prevent the internal chemistry from reacting with atmospheric humidity. If the amount of water entering the cell exceeds this limit, the electrolyte begins to break down and form hydrofluoric acid.
This threshold is typically measured in milligrams of water per year.
Hermetic Seal
Integrity of the gaskets and welds determines how well the enclosure resists the environment. A strict moisture ingress threshold requires the use of laser welding or glass to metal seals on the terminal feedthroughs. Testing these seals involves helium leak detection or specialized moisture sensors.
Chemical Degradation
Reaction between lithium hexafluorophosphate and water produces corrosive byproducts. Once the moisture ingress threshold is breached, the internal resistance of the cell increases rapidly. This process reduces the available power and can lead to the swelling of the cell casing.
Physical damage to the electrode surfaces becomes irreversible once the acid concentration rises.
Operational Lifetime
Long term storage capability depends on maintaining a dry internal environment. A battery designed with a low moisture ingress threshold can remain on a shelf for years without losing its performance characteristics. In contrast, poorly sealed cells fail much earlier in humid climates.
Manufacturers use accelerated aging tests at high humidity to verify that the enclosure design meets the required specifications for the intended market.