Meaning
Liquid metal droplets generated during the initial spray formation undergo further fragmentation in high-velocity gas flows. This subsequent fragmentation is governed by secondary breakup dynamics, which dictate the final size of the powder particles. The process occurs downstream of the nozzle exit where the relative velocity difference is highest.
Understanding this mechanism is key to producing the ultra-fine powders needed for battery applications.
Breakup Mechanism
Hydrodynamic drag forces overcome the internal cohesive forces of the droplet, leading to deformation and eventual rupture. Depending on the intensity of the gas flow, this rupture can occur through bag breakup, stripping, or catastrophic fragmentation. Catastrophic breakup is the most violent mode and yields the smallest droplets.
Weber Number
The dimensionless Weber number is used to predict which breakup mode will occur in a given flow field. This value represents the ratio of inertial drag forces to the surface tension of the droplet. High Weber numbers correspond to more energetic breakup regimes and finer final powder sizes.
Powder Refinement
Maximizing secondary fragmentation reduces the average particle size of the batch without requiring higher melt temperatures. This optimization lowers the energy costs of the atomization plant and increases the yield of high-value fine powders.