Meaning
Fluid transport phenomena describe the behavior of liquids whose viscosity changes under the influence of applied shear stress. This non-linear relationship, termed non-newtonian flow, is characteristic of the dense active material slurries used to coat battery electrodes. Sourcing and process engineers analyze these flow characteristics to design mixing and coating systems that handle variable resistance.
Correctly managing this behavior prevents slurry clogging and ensures a uniform coating thickness across the foil.
Slurry Behavior
Shear-thinning fluids experience a decrease in viscosity as the shear rate increases, which allows them to flow more easily during high-speed slot-die coating. The polymeric binders and suspended active material particles align in the direction of the flow under high shear. This alignment reduces the internal friction of the mixture.
Process Design
Pumping systems must be specified with adjustable flow rates to accommodate the varying viscosity of the flowing slurry. Low shear regions in the piping can lead to high viscosity and localized stagnation, which causes the slurry to dry or settle. Engineers use rheological modeling to prevent these flow anomalies and maintain a continuous production stream.
Sourcing Metric
Sourcing specifications for battery slurries and binders mandate a detailed shear rate sweep to characterize the flow curve. Suppliers must demonstrate that their raw materials maintain consistent non-newtonian flow profiles from batch to batch. This consistency ensures that the material behaves predictably in the coating line.