Meaning
Viscous material that exhibits a time dependent decrease in viscosity under shear stress flows easily when pumped but remains stable when at rest. This rheological behavior is characteristic of a thixotropic fluid, and it is utilized in thermal interface materials and adhesives for battery assembly. This property allows the paste to be dispensed rapidly through narrow nozzles under high pressure and then stay in place without slumping once applied.
This stability is critical for maintaining the shape of the adhesive bead before the components are mated.
Rheological Behavior
The internal structure of the material breaks down under mechanical shear, allowing the molecules and filler particles to slide past each other. Once the shear force is removed, the material gradually rebuilds its internal network and returns to its high viscosity state. This rebuild time must be carefully controlled to allow for assembly adjustments without causing the adhesive to run off the surface.
Sourcing managers must specify both the shear thinned viscosity and the recovery time for these materials.
Dispensing Advantages
Viscous pastes with these properties can be dispensed with high precision and low risk of dripping from the nozzle. The high shear rate during the pumping cycle liquefies the material, reducing the force required from the automated dispensing system. Once the material lands on the substrate, it immediately solidifies, preserving the height and width of the dispensed bead.
This behavior minimizes material waste and ensures consistent coverage across all parts.
Assembly Implications
When the battery cell is pressed into the adhesive, the displacement creates a high shear rate that allows the fluid to spread evenly. This spreading behavior ensures complete wetting of the surfaces, which is necessary for maximizing both thermal transfer and physical adhesion. After the assembly is complete, the fluid returns to its high viscosity state, holding the components in place while the adhesive cures.
This temporary holding action reduces the need for expensive mechanical fixtures.